Periodic table

The periodic table of the chemical elements (also periodic table of the elements or just the periodic table) is a tabular display of the chemical elements. Although precursors to this table exist, its invention is generally credited to Russian chemist Dmitri Mendeleev in 1869, who intended the table to illustrate recurring ("periodic") trends in the properties of the elements. The layout of the table has been refined and extended over time, as new elements have been discovered, and new theoretical models have been developed to explain chemical behavior.^[1]
The periodic table is now ubiquitous within the academic discipline of chemistry, providing a useful framework to classify, systematize, and compare all of the many different forms of chemical behavior. The table has found many applications in chemistry, physics, biology, and engineering, especially chemical engineering. The current standard table contains 118 elements to date. (elements 1–118).

Contents [hide] 1 Structure 2 Alternative versions 3 Classification 3.1 Groups 3.2 Periods 3.3 Blocks 3.4 Other 4 Periodicity of chemical properties 4.1 Trends of groups 4.2 Trends of periods 5 History 6 Gallery 7 See also 8 Notes 9 References 10 Further reading 11 External links

Structure

Group #	1	2	3	4	5	6	7	8	9	10	11	12	13	14	15	16	17	18
Period
1	1 H																	2 He
2	3 Li	4 Be											5 B	6 C	7 N	8 O	9 F	10 Ne
3	11 Na	12 Mg											13 Al	14 Si	15 P	16 S	17 Cl	18 Ar
4	19 K	20 Ca	21 Sc	22 Ti	23 V	24 Cr	25 Mn	26 Fe	27 Co	28 Ni	29 Cu	30 Zn	31 Ga	32 Ge	33 As	34 Se	35 Br	36 Kr
5	37 Rb	38 Sr	39 Y	40 Zr	41 Nb	42 Mo	43 Tc	44 Ru	45 Rh	46 Pd	47 Ag	48 Cd	49 In	50 Sn	51 Sb	52 Te	53 I	54 Xe
6	55 Cs	56 Ba	*	72 Hf	73 Ta	74 W	75 Re	76 Os	77 Ir	78 Pt	79 Au	80 Hg	81 Tl	82 Pb	83 Bi	84 Po	85 At	86 Rn
7	87 Fr	88 Ra	**	104 Rf	105 Db	106 Sg	107 Bh	108 Hs	109 Mt	110 Ds	111 Rg	112 Cn	113 Uut	114 Uuq	115 Uup	116 Uuh	117 Uus	118 Uuo
* Lanthanoids			57 La	58 Ce	59 Pr	60 Nd	61 Pm	62 Sm	63 Eu	64 Gd	65 Tb	66 Dy	67 Ho	68 Er	69 Tm	70 Yb	71 Lu
** Actinoids			89 Ac	90 Th	91 Pa	92 U	93 Np	94 Pu	95 Am	96 Cm	97 Bk	98 Cf	99 Es	100 Fm	101 Md	102 No	103 Lr

This common arrangement of the periodic table separates the lanthanoids and actinoids (the f-block) from other elements. The wide periodic table incorporates the f-block. The extended periodic table adds the 8th and 9th periods, incorporating the f-block and adding the theoretical g-block.

Element categories in the periodic table Metals Metalloids Nonmetals Unknown chemical properties Alkali metals Alkaline earth metals Inner transition elements Transition elements Other metals Other nonmetals Halogens Noble gases Lanthanides Actinides
Atomic number colors show state at standard temperature and pressure (0 °C and 1 atm) Solids Liquids Gases Unknown	Borders show natural occurrence Primordial From decay Synthetic (Undiscovered)

Classification

Groups

Main article: Group (periodic table)

A group or family is a vertical column in the periodic table. Groups are considered the most important method of classifying the elements. In some groups, the elements have very similar properties and exhibit a clear trend in properties down the group. These groups tend to be given trivial (unsystematic) names, e.g., the alkali metals, alkaline earth metals, halogens, pnictogens, chalcogens, and noble gases. Some other groups in the periodic table display fewer similarities and/or vertical trends (for example Group 14), and these have no trivial names and are referred to simply by their group numbers.

Periods

Main article: Period (periodic table)

A period is a horizontal row in the periodic table. Although groups are the most common way of classifying elements, there are some regions of the periodic table where the horizontal trends and similarities in properties are more significant than vertical group trends. This can be true in the d-block (or "transition metals"), and especially for the f-block, where the lanthanides and actinides form two substantial horizontal series of elements.

Blocks

This diagram shows the periodic table blocks.

Main article: Periodic table block

Because of the importance of the outermost shell, the different regions of the periodic table are sometimes referred to as periodic table blocks, named according to the subshell in which the "last" electron resides. The s-block comprises the first two groups (alkali metals and alkaline earth metals) as well as hydrogen and helium. The p-block comprises the last six groups (groups 13 through 18) and contains, among others, all of the semimetals. The d-block comprises groups 3 through 12 and contains all of the transition metals. The f-block, usually offset below the rest of the periodic table, comprises the rare earth metals.

Other

The chemical elements are also grouped together in other ways. Some of these groupings are often illustrated on the periodic table, such as transition metals, poor metals, and metalloids. Other informal groupings exist, such as the platinum group and the noble metals.

Periodicity of chemical properties

The main value of the periodic table is the ability to predict the chemical properties of an element based on its location on the table. It should be noted that the properties vary differently when moving vertically along the columns of the table than when moving horizontally along the rows.

Trends of groups

Modern quantum mechanical theories of atomic structure explain group trends by proposing that elements within the same group have the same electron configurations in their valence shell, which is the most important factor in accounting for their similar properties. Elements in the same group also show patterns in their atomic radius, ionization energy, and electronegativity. From top to bottom in a group, the atomic radii of the elements increase. Since there are more filled energy levels, valence electrons are found farther from the nucleus. From the top, each successive element has a lower ionization energy because it is easier to remove an electron since the atoms are less tightly bound. Similarly, a group will also see a top to bottom decrease in electronegativity due to an increasing distance between valence electrons and the nucleus.

Trends of periods

Periodic trend for ionization energy. Each period begins at a minimum for the alkali metals, and ends at a maximum for the noble gases.

Elements in the same period show trends in atomic radius, ionization energy, electron affinity, and electronegativity. Moving left to right across a period, atomic radius usually decreases. This occurs because each successive element has an added proton and electron which causes the electron to be drawn closer to the nucleus. This decrease in atomic radius also causes the ionization energy to increase when moving from left to right across a period. The more tightly bound an element is, the more energy is required to remove an electron. Similarly, electronegativity will increase in the same manner as ionization energy because of the amount of pull that is exerted on the electrons by the nucleus. Electron affinity also shows a slight trend across a period. Metals (left side of a period) generally have a lower electron affinity than nonmetals (right side of a period) with the exception of the noble gases.

History

Main article: History of the periodic table

In 1789, Antoine Lavoisier published a list of 33 chemical elements. Although Lavoisier grouped the elements into gases, metals, non-metals, and earths, chemists spent the following century searching for a more precise classification scheme. In 1829, Johann Wolfgang Döbereiner observed that many of the elements could be grouped into triads (groups of three) based on their chemical properties. Lithium, sodium, and potassium, for example, were grouped together as being soft, reactive metals. Döbereiner also observed that, when arranged by atomic weight, the second member of each triad was roughly the average of the first and the third.^[4] This became known as the Law of triads.^{[citation needed]} German chemist Leopold Gmelin worked with this system, and by 1843 he had identified ten triads, three groups of four, and one group of five. Jean Baptiste Dumas published work in 1857 describing relationships between various groups of metals. Although various chemists were able to identify relationships between small groups of elements, they had yet to build one scheme that encompassed them all.^[4]
German chemist August Kekulé had observed in 1858 that carbon has a tendency to bond with other elements in a ratio of one to four. Methane, for example, has one carbon atom and four hydrogen atoms. This concept eventually became known as valency. In 1864, fellow German chemist Julius Lothar Meyer published a table of the 49 known elements arranged by valency. The table revealed that elements with similar properties often shared the same valency.^[5]
English chemist John Newlands published a series of papers in 1864 and 1865 that described his attempt at classifying the elements: When listed in order of increasing atomic weight, similar physical and chemical properties recurred at intervals of eight, which he likened to the octaves of music.^[6][7] This law of octaves, however, was ridiculed by his contemporaries.^[8]

Portrait of Dmitri Mendeleev

Russian chemistry professor Dmitri Ivanovich Mendeleev and Julius Lothar Meyer independently published their periodic tables in 1869 and 1870, respectively. They both constructed their tables in a similar manner: by listing the elements in a row or column in order of atomic weight and starting a new row or column when the characteristics of the elements began to repeat.^[9] The success of Mendeleev's table came from two decisions he made: The first was to leave gaps in the table when it seemed that the corresponding element had not yet been discovered.^[10] Mendeleev was not the first chemist to do so, but he went a step further by using the trends in his periodic table to predict the properties of those missing elements, such as gallium and germanium.^[11] The second decision was to occasionally ignore the order suggested by the atomic weights and switch adjacent elements, such as cobalt and nickel, to better classify them into chemical families. With the development of theories of atomic structure, it became apparent that Mendeleev had inadvertently listed the elements in order of increasing atomic number.^[12]
With the development of modern quantum mechanical theories of electron configurations within atoms, it became apparent that each row (or period) in the table corresponded to the filling of a quantum shell of electrons. In Mendeleev's original table, each period was the same length. However, because larger atoms have more electron sub-shells, modern tables have progressively longer periods further down the table.^[13]
In the years that followed after Mendeleev published his periodic table, the gaps he left were filled as chemists discovered more chemical elements. The last naturally occurring element to be discovered was francium (referred to by Mendeleev as eka-caesium) in 1939.^[14] The periodic table has also grown with the addition of synthetic and transuranic elements. The first transuranic element to be discovered was neptunium, which was formed by bombarding uranium with neutrons in a cyclotron in 1939.^[15]